Prototypical Transition-Metal Carbenes, (CO)5CrCH2, (CO)4FeCH2, (CO)3NiCH2, (CO)5MoCH2, (CO)4RuCH2, (CO)3PdCH2, (CO)5WCH2, (CO)4OsCH2, and (CO)3PtCH2: Challenge to Experiment

Transition-metal carbenes are useful in organometallic chemistry due to their demonstrated use as catalysts in carbon–carbon bond-forming reactions. Yet the prototypical transition-metal carbenes, consisting of a single metal center doubly bonded to a methylene ligand and surrounded by carbonyls, ha...

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Bibliographic Details
Published in:The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2018-08, Vol.122 (32), p.6570-6577
Main Authors: Weidman, Jared D, Estep, Marissa L, Schaefer, Henry F
Format: Article
Language:English
Online Access:Get full text
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