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Electric Field Control of Metal–Insulator Transition in Charge-Ordered Fe2BO4
The structure and electric properties of single-crystal Fe2BO4 are measured by in situ high-resolution X-ray diffraction combined with current–voltage (I–V) measurements. A superstructure due to charge ordering (CO) is found at room temperature, and the superstructure peak disappears when the applie...
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Published in: | ACS applied electronic materials 2024-05, Vol.6 (5), p.3078-3083 |
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Main Authors: | , , , , , , |
Format: | Article |
Language: | English |
Online Access: | Get full text |
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Summary: | The structure and electric properties of single-crystal Fe2BO4 are measured by in situ high-resolution X-ray diffraction combined with current–voltage (I–V) measurements. A superstructure due to charge ordering (CO) is found at room temperature, and the superstructure peak disappears when the applied electric field exceeds a certain threshold. I–V characteristics show a sharp resistance drop, indicating a metal–insulator transition (MIT) induced by applied voltage and revealing electron–lattice coupling, which is due to the Joule heating effect. Moreover, the Fe2BO4 single crystal exhibits a multidomain monoclinic phase in its original state, which transforms into a single-domain orthorhombic phase when a voltage of 200 V is applied. MIT, CO state collapse, and structural phase change have been observed simultaneously and indicate that the CO structural phase change can be controlled by an electric field. |
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ISSN: | 2637-6113 2637-6113 |
DOI: | 10.1021/acsaelm.4c00359 |