Luminescent Phosphine Gold(I) Thiolates:  Correlation between Crystal Structure and Photoluminescent Properties in [R3PAu{SC(OMe)NC6H4NO2-4}] (R = Et, Cy, Ph) and [(Ph2P-R-PPh2){AuSC(OMe)NC6H4NO2-4}2] (R = CH2, (CH2)2, (CH2)3, (CH2)4, Fc)

X-ray crystallography shows the gold atoms in [R3PAu{SC(OMe)NC6H4NO2-4}] (R = Et, Cy, Ph; 1−3, respectively) and [(Ph2P-R-PPh2){AuSC(OMe)NC6H4NO2-4}2] (R = CH2, (CH2)2, (CH2)3, (CH2)4, Fc; 4−8, respectively) are linearly coordinated by phosphorus and thiolate-sulfur; weak intramolecular Au···O int...

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Bibliographic Details
Published in:Inorganic chemistry 2006-10, Vol.45 (20), p.8165-8174
Main Authors: Ho, Soo Yei, Cheng, Eddie Chung-Chin, Tiekink, Edward R. T, Yam, Vivian Wing-Wah
Format: Article
Language:English
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