[Cu81(PhS)46( t BuNH2)10(H)32]3+ Reveals the Coexistence of Large Planar Cores and Hemispherical Shells in High-Nuclearity Copper Nanoclusters

Copper-based nanomaterials have attracted tremendous interest due to their unique properties in the fields of photoluminescence and catalysis. As a result, studies on the correlation between their molecular structure and their properties are of great importance. Copper nanoclusters are a new class o...

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Bibliographic Details
Published in:Journal of the American Chemical Society 2020-05, Vol.142 (19), p.8696-8705
Main Authors: Huang, Ren-Wu, Yin, Jun, Dong, Chunwei, Ghosh, Atanu, Alhilaly, Mohammad J, Dong, Xinglong, Hedhili, Mohamed Nejib, Abou-Hamad, Edy, Alamer, Badriah, Nematulloev, Saidkhodzha, Han, Yu, Mohammed, Omar F, Bakr, Osman M
Format: Article
Language:English
Subjects:
catalytic activity
copper
copper nanoparticles
crystal structure
density functional theory
electrospray ionization mass spectrometry
hydrogen production
ligands
nuclear magnetic resonance spectroscopy
photoluminescence
X-ray diffraction
X-ray photoelectron spectroscopy
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