Renaissance of Homogeneous Cerium Catalysts with Unique     Ce(IV/III) Couple: Redox-Mediated Organic Transformations Involving Homolysis of Ce(IV)–Ligand Covalent Bonds

Recent advances in the catalytic application of cerium complexes were achieved through controlling the Ce­(IV/III) redox couple. Although Ce­(IV) complexes have been extensively investigated as stoichiometric oxidants in organic synthesis on the basis of their highly positive redox potentials, these...

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Bibliographic Details
Published in:Journal of the American Chemical Society 2021-06, Vol.143 (21), p.7879-7890
Main Authors: Tsurugi, Hayato, Mashima, Kazushi
Format: Article
Language:English
Subjects:
catalysts
catalytic activity
cerium
chemical bonding
copper
homolytic cleavage
ligands
nickel
oxygen
stoichiometry
zinc
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