Calix[4]pyrrolato-germane-(thf)2: Unlocking the Anti-van’t Hoff–Le Bel Reactivity of Germanium(IV) by Ligand Dissociation

Anti-van’t Hoff–Le Bel configured p-block element species possess intrinsically high reactivity and are thus challenging to isolate. Consequently, numerous elements in this configuration, including square-planar germanium­(IV), remain unexplored. Herein, we follow a concept to reach anti-van’t Hoff–...

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Bibliographic Details
Published in:Journal of the American Chemical Society 2023-08, Vol.145 (32), p.17746-17754
Main Authors: Yadav, Ravi, Janßen, Paul, Schorpp, Marcel, Greb, Lutz
Format: Article
Language:English
Subjects:
acidity
alcohols
dissociation
fluorides
germanium
ligands
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