Generation of Phosphoranyl Radicals via Photoredox Catalysis Enables Voltage–Independent Activation of Strong C–O Bonds

Despite the prevalence of alcohols and carboxylic acids as functional groups in organic molecules and the potential to serve as radical precursors, C–O bonds remain difficult to activate. We report a synthetic strategy for direct access to both alkyl and acyl radicals from these ubiquitous functiona...

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Bibliographic Details
Published in:ACS catalysis 2018-12, Vol.8 (12), p.11134-11139
Main Authors: Stache, Erin E, Ertel, Alyssa B, Rovis, Tomislav, Doyle, Abigail G
Format: Article
Language:English
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