Proton Delivery and Removal in [Ni(PR 2NR′ 2)2]2+ Hydrogen Production and Oxidation Catalysts

To examine the role of proton delivery and removal in the electrocatalytic oxidation and production of hydrogen by [Ni(PR 2NR′ 2)2]2+ (where PR 2NR′ 2 is 1,5-R′-3,7-R-1,5-diaza-3,7-diphosphacyclooctane), we report experimental and theoretical studies of the intermolecular proton exchange reactions u...

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Bibliographic Details
Published in:	Journal of the American Chemical Society 2012-11, Vol.134 (47), p.19409-19424
Main Authors:	O’Hagan, Molly, Ho, Ming-Hsun, Yang, Jenny Y, Appel, Aaron M, DuBois, M. Rakowski, Raugei, Simone, Shaw, Wendy J, DuBois, Daniel L, Bullock, R. Morris
Format:	Article
Language:	English
Subjects:	Catalysis catalysts chemical bonding Environmental Molecular Sciences Laboratory hydrogen Hydrogen - chemistry hydrogen production INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY isomerization isomers Kinetics Models, Molecular Molecular Conformation nickel Nickel - chemistry Organometallic Compounds - chemistry oxidation Oxidation-Reduction Protons
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