Investigation of the Electronic Ground States for a Reduced Pyridine(diimine) Uranium Series: Evidence for a Ligand Tetraanion Stabilized by a Uranium Dimer

The electronic structures of a series of highly reduced uranium complexes bearing the redox-active pyridine(diimine) ligand, MesPDIMe (MesPDIMe = 2,6-(2,4,6-Me3-C6H2-NCMe)2C5H3N) have been investigated. The complexes, (MesPDIMe)UI3(THF) (1), (MesPDIMe)UI2(THF)2 (2), [(MesPDIMe)UI]2 (3), and [(M...

Full description

Saved in:

Bibliographic Details
Published in:	Journal of the American Chemical Society 2015-04, Vol.137 (14), p.4690-4700
Main Authors:	Anderson, Nickolas H, Odoh, Samuel O, Williams, Ursula J, Lewis, Andrew J, Wagner, Gregory L, Lezama Pacheco, Juan, Kozimor, Stosh A, Gagliardi, Laura, Schelter, Eric J, Bart, Suzanne C
Format:	Article
Language:	English
Subjects:	cations Dimerization Electrons enthalpy Ligands Magnetic Phenomena Models, Molecular Molecular Conformation Organometallic Compounds - chemistry Oxidation-Reduction pyridines Pyridines - chemistry Quantum Theory uranium Uranium - chemistry
Citations:	Items that this one cites Items that cite this one
Online Access:	Get full text
Tags:	Add Tag No Tags, Be the first to tag this record!