Inverting Steric Effects: Using “Attractive” Noncovalent Interactions To Direct Silver-Catalyzed Nitrene Transfer

Nitrene transfer (NT) reactions represent powerful and direct methods to convert C–H bonds into amine groups that are prevalent in many commodity chemicals and pharmaceuticals. The importance of the C–N bond has stimulated the development of numerous transition-metal complexes to effect chemo-, regi...

Full description

Saved in:
Bibliographic Details
Published in:Journal of the American Chemical Society 2017-12, Vol.139 (48), p.17376-17386
Main Authors: Huang, Minxue, Yang, Tzuhsiung, Paretsky, Jonathan D, Berry, John F, Schomaker, Jennifer M
Format: Article
Language:English
Subjects:
Amination
carbon-hydrogen bond activation
Catalysis
catalysts
chemical bonding
diastereoselectivity
drugs
energy
Imines - chemistry
Ligands
silver
Silver - chemistry
Transition Elements - chemistry
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!