Synthesis of Iron P‑N-P′ and P‑NH-P′ Asymmetric Hydrogenation Catalysts

Complexes of the type mer,trans-[Fe­(P-N-P′)­(CO)2Br]­BF4 are known to be precatalysts for the asymmetric direct hydrogenation of ketones and imines. Employing related ligand scaffolds, we successfully generated and tested the series of three new precatalysts [Fe­(PCy2CH2CHNCH­(R)­CH2PPh2)­(CO)2Br]...

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Bibliographic Details
Published in:Organometallics 2014-11, Vol.33 (22), p.6452-6465
Main Authors: Sonnenberg, Jessica F, Lough, Alan J, Morris, Robert H
Format: Article
Language:English
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