Synthesis, characterization, photophysical properties, and catalytic activity of an SCS bis(N-heterocyclicthione) (SCS-NHT) Pd pincer complex

Treatment of 1,3-bis(3′-butylimidazolyl-1′-yl)benzene diiodide with elemental sulfur in the presence of a base produced a bis(N-heterocyclic thione) (NHT) pincer ligand precursor. Its reaction with PdCl 2 (CH 3 CN) 2 produced chloro[1,3-bis(3′-butylimidazole-2′-thione-κ- S )benzene-κ- C ]palladium(...

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2015-08, Vol.44 (32), p.14475-14482
Main Authors: Tyson, Ginger E., Tokmic, Kenan, Oian, Casey S., Rabinovich, Daniel, Valle, Henry U., Hollis, T. Keith, Kelly, John T., Cuellar, Kristina A., McNamara, Louis E., Hammer, Nathan I., Webster, Charles Edwin, Oliver, Allen G., Zhang, Min
Format: Article
Language:English
Subjects:
Catalytic activity
Chemical reactions
Ligands
Molecular structure
Palladium
Precursors
Synthesis
X-rays
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