Syntheses, crystal structures, and magnetic properties of a family of heterometallic octanuclear [Cu 6 Ln 2 ] (Ln = Dy( iii ), Tb( iii ), Ho( iii ), Er( iii ), and Gd( iii )) complexes

A new family of octanuclear Cu–Ln complexes, [Cu 6 Ln 2 (tea) 2 (py) 2 CO 2 3 Cl 6 ]· x H 2 O (Ln = Dy ( 1 ), Tb ( 2 ), Ho ( 3 ), Er ( 4 ), Gd ( 5 ); x = 1 for 1 , 3 and 5 , x = 0 for 2 and x = 7 for 4 ; (py) 2 CO 2 H 2 = the gem -diol form of di-2-pyridyl ketone, teaH 3 = triethanolamine), has been...

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Bibliographic Details
Published in:New journal of chemistry 2017, Vol.41 (13), p.5884-5892
Main Authors: Wang, Hui-Sheng, Yang, Feng-Jun, Long, Qiao-Qiao, Huang, Zhi-Yong, Chen, Wei, Pan, Zhi-Quan
Format: Article
Language:English
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