The synthesis, chain-packing simulation and long-term gas permeability of highly selective spirobifluorene-based polymers of intrinsic microporosity

Membranes composed of Polymers of Intrinsic Microporosity (SBF-PIMs) have potential for commercial gas separation. Here we report a combined simulation and experimental study to investigate the effect on polymer microporosity and gas permeability by placing simple substituents such as methyl, t -but...

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Bibliographic Details
Published in:Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2018, Vol.6 (22), p.10507-10514
Main Authors: Bezzu, C. Grazia, Carta, Mariolino, Ferrari, Maria-Chiara, Jansen, Johannes C., Monteleone, Marcello, Esposito, Elisa, Fuoco, Alessio, Hart, Kyle, Liyana-Arachchi, T. P., Colina, Coray M., McKeown, Neil B.
Format: Article
Language:English
Subjects:
Aging (natural)
air
Biogas
Carbon dioxide
Chemical synthesis
Gas permeation
Gas separation
Gas transport
Membrane permeability
methane
micropores
Microporosity
moieties
Natural gas
nitrogen
Nitrogen enrichment
oxygen
Oxygen enrichment
Permeability
Polymers
Powder injection molding
Upper bounds
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