Aminodealkenylation: Ozonolysis and copper catalysis convert C(sp 3 )–C(sp 2 ) bonds to C(sp 3 )–N bonds

Great efforts have been directed toward alkene π bond amination. In contrast, analogous functionalization of the adjacent C(sp 3 )–C(sp 2 ) σ bonds is much rarer. Here we report how ozonolysis and copper catalysis under mild reaction conditions enable alkene C(sp 3 )–C(sp 2 ) σ bond–rupturing cross-...

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Bibliographic Details
Published in:Science (American Association for the Advancement of Science) 2023-08, Vol.381 (6660), p.877-886
Main Authors: He, Zhiqi, Moreno, Jose Antonio, Swain, Manisha, Wu, Jason, Kwon, Ohyun
Format: Article
Language:English
Subjects:
Bonding
Carbon
Carbon compounds
Catalysis
Copper
Copper converters
Nitrogen
Terpenes
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