Photoredox-Catalyzed Dimerization of Arylalkenes via an Oxidative [4+2] Cycloaddition Sequence: Synthesis of Naphthalene Derivatives

We report a radical cation [4+2] annulation of arylalkenes to afford naphthalene derivatives using an organic photosensitizer (9‐mesityl‐10‐methylacridinium perchlorate) under visible light photocatalysis. In the presence of oxygen (in the air), the oxidative dimerization/intramolecular [4+2] cycloa...

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Bibliographic Details
Published in:Advanced synthesis & catalysis 2016-12, Vol.358 (23), p.3887-3896
Main Authors: Wei, Donglei, Li, Yanru, Liang, Fushun
Format: Article
Language:English
Subjects:
[4+2] cycloaddition
cascade reaction
Cycloaddition
Derivatives
Dimerization
Naphthalene
naphthalene derivatives
Organic chemistry
Photocatalysis
radical cations
Radicals
styrene derivatives
Synthesis (chemistry)
visible light photocatalysis
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