Hyperfine‐Interaction‐Driven Suppression of Quantum Tunneling at Zero Field in a Holmium(III) Single‐Ion Magnet

An extremely rare non‐Kramers holmium(III) single‐ion magnet (SIM) is reported to be stabilized in the pentagonal‐bipyramidal geometry by a phosphine oxide with a high energy barrier of 237(4) cm−1. The suppression of the quantum tunneling of magnetization (QTM) at zero field and the hyperfine struc...

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2017-04, Vol.56 (18), p.4996-5000
Main Authors: Chen, Yan‐Cong, Liu, Jun‐Liang, Wernsdorfer, Wolfgang, Liu, Dan, Chibotaru, Liviu F., Chen, Xiao‐Ming, Tong, Ming‐Liang
Format: Article
Language:English
Subjects:
Abundance
Chemical Sciences
Energy
Holmium
hyperfine interactions
Hysteresis
Hysteresis loops
lanthanides
Magnetic permeability
magnetic properties
Magnetic susceptibility
Magnetization
Phosphine
Phosphine oxide
Quantum tunnelling
Single crystals
single-molecule magnets
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