An Electron‐Rich Cyclic (Alkyl)(Amino)Carbene on Au(111), Ag(111), and Cu(111) Surfaces

The structural properties and binding motif of a strongly σ‐electron‐donating N‐heterocyclic carbene have been investigated on different transition‐metal surfaces. The examined cyclic (alkyl)(amino)carbene (CAAC) was found to be mobile on surfaces, and molecular islands with short‐range order could...

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2020-08, Vol.59 (32), p.13643-13646
Main Authors: Bakker, Anne, Freitag, Matthias, Kolodzeiski, Elena, Bellotti, Peter, Timmer, Alexander, Ren, Jindong, Schulze Lammers, Bertram, Moock, Daniel, Roesky, Herbert W., Mönig, Harry, Amirjalayer, Saeed, Fuchs, Harald, Glorius, Frank
Format: Article
Language:English
Subjects:
CAAC
Catalysts
Communication
Communications
Copper
Density functional theory
Gold
gold surfaces
ligands
Metal surfaces
Photoelectron spectroscopy
Photoelectrons
scanning probe microscopy
Scanning tunneling microscopy
Silver
X-ray photoelectron spectroscopy
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