A Red‐Light‐Driven CO‐Releasing Complex: Photoreactivities and Excited‐State Dynamics of Highly Distorted Tricarbonyl Rhenium Phthalocyanines

How to activate a Re−CO bond: Carbon monoxide‐releasing molecules (CORMs) have attracted significant attention because of the vasorelaxation effect of CO. When a phthalocyanine ligand was used, the Re−CO bonds were successfully activated by a low‐energy photon of red light, which can penetrate deepl...

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Bibliographic Details
Published in:Chemistry : a European journal 2022-08, Vol.28 (48), p.n/a
Main Authors: Wang, Mengfei, Murata, Kei, Koike, Yosuke, Jonusauskas, Gediminas, Furet, Amaury, Bassani, Dario M., Saito, Daisuke, Kato, Masako, Shimoda, Yuushi, Miyata, Kiyoshi, Onda, Ken, Ishii, Kazuyuki
Format: Article
Language:English
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Summary:How to activate a Re−CO bond: Carbon monoxide‐releasing molecules (CORMs) have attracted significant attention because of the vasorelaxation effect of CO. When a phthalocyanine ligand was used, the Re−CO bonds were successfully activated by a low‐energy photon of red light, which can penetrate deeply into living tissues. Thus, this study provides key insights and a foundation for designing photoCORMs for biological or therapeutic applications. More information can be found in the Research Article by M. Kato, K. Onda, K. Ishii, and co‐workers (DOI: 10.1002/chem.202200716).
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.202202281