Gold(I)-Catalyzed Tandem Rearrangement-Nucleophilic Substitution of α-Acetoxy Alkynyl Oxiranes or Aziridines: Efficient Approach to Furans and Pyrroles

Highly substituted furans and pyrroles were efficiently formed by a new gold(I)‐catalyzed tandem rearrangement–nucleophilic substitution of acetoxylated alkynyl oxiranes and aziridines in the presence of various nucleophiles. Highly substituted furans and pyrroles were efficiently formed by a new go...

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Bibliographic Details
Published in:European Journal of Organic Chemistry 2010-03, Vol.2010 (9), p.1644-1647
Main Authors: Blanc, Aurélien, Alix, Aurélien, Weibel, Jean-Marc, Pale, Patrick
Format: Article
Language:English
Subjects:
Catalysis
Chemistry
Cyclization
Exact sciences and technology
General and physical chemistry
Gold
Heterocyclic compounds
Heterocyclic compounds with o, s, se, te hetero atom and condensed derivatives
Heterocyclic compounds with only one n hetero atom and condensed derivatives
Homogeneous catalysis
Kinetics and mechanisms
Nitrogen heterocycles
Organic chemistry
Oxygen heterocycles
Preparations and properties
Reactivity and mechanisms
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
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Summary:Highly substituted furans and pyrroles were efficiently formed by a new gold(I)‐catalyzed tandem rearrangement–nucleophilic substitution of acetoxylated alkynyl oxiranes and aziridines in the presence of various nucleophiles. Highly substituted furans and pyrroles were efficiently formed by a new gold(I)‐catalyzed tandem rearrangement–nucleophilic substitution of acetoxylated alkynyl oxiranes and aziridines in the presence of various nucleophiles.
ISSN:1434-193X
1099-0690
DOI:10.1002/ejoc.200901331