Aminocatalytic Enantioselective 1, 6‐Addition of (Nitromethyl)benzenes to α, β, γ, δ‐Cyclic Dienones

An excellent regio‐, and enantioselective 1,6‐addition of (nitromethyl)benzenes to α, β, γ, δ‐cyclic dienones via nitro‐Michael reactions has been developed. With the application of cinchona‐based primary amine catalysts, various chiral ε‐nitro ketene compounds were obtained in moderate to high yiel...

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Bibliographic Details
Published in:European journal of organic chemistry 2019-10, Vol.2019 (39), p.6626-6630
Main Authors: Feng, Kai‐Xiang, Shen, Qiao‐Yu, Zheng, Ya‐Yun, Xia, Ai‐Bao, Zhou, Zhan‐Yu, Tang, Cheng‐Ke, Zhong, Ai‐Guo, Xu, Dan‐Qian, Du, Xiao‐Hua
Format: Article
Language:English
Subjects:
(Nitromethyl)benzene
1,6‐Addition
Asymmetric catalysis
Enantiomers
Organocatalysis
α, β, γ, δ‐Cyclic dienone
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