Macromol. Rapid Commun. 2/2014

Front Cover: A possible strategy to encrypt information at the molecular level is the creation of a binary code using two co‐monomers defined as 0 and 1. As a proof of principle, sequence‐defined oligo(triazole amide)s are synthesized via a stepwise solid‐phase iterative process. In this approach, a...

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Bibliographic Details
Published in:Macromolecular rapid communications. 2014-01, Vol.35 (2), p.113-113
Main Authors: Trinh, Thanh Tam, Oswald, Laurence, Chan-Seng, Delphine, Lutz, Jean-François
Format: Article
Language:English
Subjects:
amidification
copper-assisted alkyne-azide cycloaddition
sequence-controlled oligomers
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Summary:Front Cover: A possible strategy to encrypt information at the molecular level is the creation of a binary code using two co‐monomers defined as 0 and 1. As a proof of principle, sequence‐defined oligo(triazole amide)s are synthesized via a stepwise solid‐phase iterative process. In this approach, a reactive spacer, namely 1‐amino‐11‐azido‐3,6,9‐trioxaundecane, is reacted with either 4‐pentynoic acid (non‐coding monomer) or 2‐methyl‐4‐pentynoic acid (coding monomer). All possible information triads, 000, 001, 010, 100, 011, 101, 110, and 111 can be obtained using this approach. Further details can be found in the article by T. T. Trinh, L. Oswald, D. Chan‐Seng, and J.‐F. Lutz* on page 141.
ISSN:1022-1336
1521-3927
DOI:10.1002/marc.201470006