Standard molar enthalpy of formation of 1-cyano-acetylpiperidine

The standard ( p 0 =0.1 MPa) molar enthalpy of formation of 1-cyanoacetylpiperidine, in the crystalline state, at T =298.15 K, has been derived from measurements of its standard massic energy of combustion, by static bomb combustion calorimetry, as Δ f H m 0 =−217.1±1.4 kJ mol −1 . The standard mola...

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Bibliographic Details
Published in:Journal of thermal analysis and calorimetry 2008-04, Vol.92 (1), p.59-62
Main Authors: Ribeiro da Silva, M. A. V., Cabral, Joana I. T. A.
Format: Article
Language:English
Subjects:
Analytical Chemistry
Chemical thermodynamics
Chemistry
Chemistry and Materials Science
Elements, mineral and organic compounds
Exact sciences and technology
General and physical chemistry
Inorganic Chemistry
Measurement Science and Instrumentation
Physical Chemistry
Polymer Sciences
Thermodynamic properties
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Summary:The standard ( p 0 =0.1 MPa) molar enthalpy of formation of 1-cyanoacetylpiperidine, in the crystalline state, at T =298.15 K, has been derived from measurements of its standard massic energy of combustion, by static bomb combustion calorimetry, as Δ f H m 0 =−217.1±1.4 kJ mol −1 . The standard molar enthalpy of sublimation was measured, at T =298.15 K, by the microcalorimetric sublimation technique as Δ cr g H m 0 =103.5±1.9 kJ mol −1 .
ISSN:1388-6150
1588-2926
1572-8943
DOI:10.1007/s10973-007-8736-x