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Studies of gas-phase clustering of water on sulphuric acid molecules
Enthalpies and free energies of gas-phase clustering of one to ten water molecules about one acid molecule are predicted from thermodynamic considerations. The enthalpy of formation of the monohydrate, H 2SO 4H 2O, −53.5 kJ/mol, compare favorably with recent calculations from quantum mechanics, −67...
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Published in: | Chemical physics letters 1991-08, Vol.183 (1), p.21-24 |
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Main Authors: | , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | Enthalpies and free energies of gas-phase clustering of one to ten water molecules about one acid molecule are predicted from thermodynamic considerations. The enthalpy of formation of the monohydrate, H
2SO
4H
2O, −53.5 kJ/mol, compare favorably with recent calculations from quantum mechanics, −67 kJ/mol. |
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ISSN: | 0009-2614 1873-4448 |
DOI: | 10.1016/0009-2614(91)85092-B |