Loading…

Studies of gas-phase clustering of water on sulphuric acid molecules

Enthalpies and free energies of gas-phase clustering of one to ten water molecules about one acid molecule are predicted from thermodynamic considerations. The enthalpy of formation of the monohydrate, H 2SO 4H 2O, −53.5 kJ/mol, compare favorably with recent calculations from quantum mechanics, −67...

Full description

Saved in:
Bibliographic Details
Published in:Chemical physics letters 1991-08, Vol.183 (1), p.21-24
Main Authors: Mirabel, Ph, Ponche, J.L.
Format: Article
Language:English
Subjects:
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Enthalpies and free energies of gas-phase clustering of one to ten water molecules about one acid molecule are predicted from thermodynamic considerations. The enthalpy of formation of the monohydrate, H 2SO 4H 2O, −53.5 kJ/mol, compare favorably with recent calculations from quantum mechanics, −67 kJ/mol.
ISSN:0009-2614
1873-4448
DOI:10.1016/0009-2614(91)85092-B