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Preparation, crystal structure, thermal and catalytical behaviour of copper diammine divanadate
A new copper diammine divanadate Cu(NH 3) 2(VO 3) 2 has been synthesized and structurally characterized. The unit cell is monoclinic, space group Pc, a = 5.616(2) A ̊ , b = 5.591(1) A ̊ , c = 11.331(2) A ̊ , β = 90.91(2)°, V = 355.7(3) A ̊ 3 , Z = 2. The thermal decomposition has been studied by the...
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Published in: | Materials research bulletin 1993, Vol.28 (1), p.45-58 |
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Main Authors: | , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | A new copper diammine divanadate Cu(NH
3)
2(VO
3)
2 has been synthesized and structurally characterized. The unit cell is monoclinic, space group Pc,
a = 5.616(2)
A
̊
,
b = 5.591(1)
A
̊
,
c = 11.331(2)
A
̊
,
β = 90.91(2)°,
V = 355.7(3)
A
̊
3
, Z = 2. The thermal decomposition has been studied by thermogravimetry and simultaneous mass spectrometry (TG/MS) in different atmospheres, i.e. H
2, N
2, He and O
2. As solid products elemental copper on V
2O
3, Cu
0.95V
2O
5 and CuV
2O
6 have been obtained, and depending on the actual atmosphere different volatile products such as NH
3, H
2O and N
2. Independent of the pretreatment, reoxidation of the product phases leads to the ternary oxide CuV
2O
6. The microstructures have been characterized by scanning electron microscopy (SEM) and high resolution electron microscopy (HREM). The product decomposed in hydrogen has been tested with respect to its catalytic activity for the reduction of NO with CO. |
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ISSN: | 0025-5408 1873-4227 |
DOI: | 10.1016/0025-5408(93)90007-Z |