Thermal properties of thio- and selenocyanatocopper(II) complexes with some N-donor ligands

The thermal decomposition of CuL2(NCS)2, CuL2(NCSe)2 and CuL2(NCS)(NCSe) where L = 2,2'-bipyridine or 1,10-phenanthroline showed that the phenanthroline complexes are thermally more stable than bipyridine complexes. The different course of the thermal decomposition curves of individual complexe...

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Bibliographic Details
Published in:Thermochimica acta 1985-09, Vol.92, p.807-810
Main Authors: Kabešová, M., Dunaj-Jurčo, M., Ondrejovič, G.
Format: Article
Language:English
Subjects:
Chemistry
Exact sciences and technology
Inorganic chemistry and origins of life
Kinetics and mechanism of reactions
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Summary:The thermal decomposition of CuL2(NCS)2, CuL2(NCSe)2 and CuL2(NCS)(NCSe) where L = 2,2'-bipyridine or 1,10-phenanthroline showed that the phenanthroline complexes are thermally more stable than bipyridine complexes. The different course of the thermal decomposition curves of individual complexes is a conse-quence of a difference in reduction properties between NCS and NCSe ligands.
ISSN:0040-6031
1872-762X
DOI:10.1016/0040-6031(85)86000-7