Polarography in diglyme and in its mixtures with water or ethanol

The addition of water or ethanol to diglyme does not change its aprotic nature while it increases the solubility of salts and the conductivity of solutions. The reduction of alkali metal cations and chloronorcaranes has been investigated in such solutions. Alkali metal catalytic currents have been o...

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Bibliographic Details
Published in:Journal of electroanalytical chemistry and interfacial electrochemistry 1984-01, Vol.180 (1), p.67-76
Main Authors: Feoktistov, L.G., Girina, G.P., Kokorekina, V.A., Alpatova, N.M., Ovsyannikova, E.V.
Format: Article
Language:English
Subjects:
Chemistry
Electrochemistry
Exact sciences and technology
General and physical chemistry
Kinetics and mechanism of reactions
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Summary:The addition of water or ethanol to diglyme does not change its aprotic nature while it increases the solubility of salts and the conductivity of solutions. The reduction of alkali metal cations and chloronorcaranes has been investigated in such solutions. Alkali metal catalytic currents have been observed in the presence of organic compounds.
ISSN:0022-0728
DOI:10.1016/0368-1874(84)83570-4