Effect of some chelating ligands on the potential response of the chalcocite copper ion-selective electrode

The effects of diethylenetriamine, triethylenetetramine, tetraethylenepentamine, aminoacetic acid, iminodiacetic acid, nitrilotriacetic acid, ethylenediaminediaminetetraacetic acid, diethylenetriaminepentaacetic acid and triethylenetetraminehexaacetic acid on the behaviour of the synthetic chalcocit...

Full description

Saved in:
Bibliographic Details
Published in:Analytica chimica acta 1984, Vol.158 (2), p.343-355
Main Authors: Hulanicki, Adam, Krawczynski Vel Krawczyk, Tadeusz, Lewenstam, Andrzej
Format: Article
Language:English
Subjects:
Chemistry
Electrochemistry
Electrodes: preparations and properties
Exact sciences and technology
General and physical chemistry
Ion selective electrodes
Miscellaneous
Other electrodes
Study of interfaces
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The effects of diethylenetriamine, triethylenetetramine, tetraethylenepentamine, aminoacetic acid, iminodiacetic acid, nitrilotriacetic acid, ethylenediaminediaminetetraacetic acid, diethylenetriaminepentaacetic acid and triethylenetetraminehexaacetic acid on the behaviour of the synthetic chalcocite (copper(I) sulphide) copper-selective electrode are described. The effects of those ligands on the electrode response at different pH values is explained on the assumption that copper(I) ions contribute to the potential indicated. Copper(I) ions originate from the membrane phase and participate in exchange and redox reactions. The effects of oxygen and temperature are reported. The electrode response can be predicted on the basis of copper(II) equilibria in solution, only if the conditions are such that there is no interference from copper(I) ions.
ISSN:0003-2670
1873-4324
DOI:10.1016/S0003-2670(00)84840-0