Stereospecific α- d-mannosylation

The stereospecific formation of α- d-mannosyl glycosidic linkages has been achieved in high yield using tetra- O-pivaloyl-α- d-mannopyranosyl fluoride and boron trifluoride diethyl etherate in dichloromethane. Examples of the α- d-mannosylation of primary, secondary, benzylic and phenolic hydroxyl g...

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Bibliographic Details
Published in:Carbohydrate research 1999-04, Vol.317 (1), p.210-216
Main Authors: Scott, Ian L., Market, Robert V., DeOrazio, Russell J., Meckler, Harold, Kogan, Timothy P.
Format: Article
Language:English
Subjects:
Glycosyl fluorides
Mannosylation
Stereospecific
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Summary:The stereospecific formation of α- d-mannosyl glycosidic linkages has been achieved in high yield using tetra- O-pivaloyl-α- d-mannopyranosyl fluoride and boron trifluoride diethyl etherate in dichloromethane. Examples of the α- d-mannosylation of primary, secondary, benzylic and phenolic hydroxyl groups are described.
ISSN:0008-6215
1873-426X
DOI:10.1016/S0008-6215(99)00065-8