A novel process and material for the separation of carbon dioxide and hydrogen sulfide gas mixtures

• Published in: Carbon (New York) 1997, Vol.35 (9), p.1279-1294
• Main Authors: Burchell, T.D., Judkins, R.R., Rogers, M.R., Williams, A.M.
• Format: Article
• Language: English
• Subjects: A. Activated carbon; A. carbon/carbon composites; Adsorbents; C. adsorption; Chemistry; Colloidal state and disperse state; D. electrical properties; D. thermal conductivity; Exact sciences and technology; General and physical chemistry; Porous materials; Surface physical chemistry
• ISSN: 0008-6223; 1873-3891
• DOI: 10.1016/S0008-6223(97)00077-8

Carbon fiber composite molecular sieve (CFCMS) synthesis and characterization of the macro-, meso- and micropore structure are reported. CFCMS physical properties, including strength, thermal conductivity and electrical resistivity, are reported and the thermal conductivity of CFCMS compared with literature data for granular activated carbon (GAC) and packed beds of GAC. Adsorption studies, including isotherms for CO 2 and CH 4 at temperatures of 30, 60 and 100 °C on CFCMS samples activated to different burn-offs, are reported. High pressure adsorption data for CO 2 and CH 4 show that the CFCMS material has sufficient selectivity for CO 2 over CH 4 for a commercial separation. Breakthrough experiments were conducted for CO 2/CH 4 and H 2S/H 2 gas mixtures and the selective separation of CO 2 and H 2S was demonstrated. The electrical conductivity of our novel monolith was exploited to effect the rapid desorption of adsorbed gases. Desorption at low applied voltage was accompanied by a heating of the CFCMS to temperatures < 100 °C. The passage of greater electrical current (∼ 14 A at 3.25 V) caused the CFCMS temperature to exceed 300 °C. During desorption, the release of adsorbed gas was noted to occur prior to a rise in CFCMS bulk temperature. It is demonstrated that the heat of adsorption is responsible for this phenomenon. The relationship between the carbon fiber structure, electrical behavior, and the desorption characteristics of CFCMS are discussed. A preliminary design of an “electrical swing adsorption” (ESA) system is outlined. Potential uses of the CFCMS/ESA technology are suggested.