Highly efficient cleavage of epoxides catalyzed by B(C 6F 5) 3

A highly effective protocol for ring opening of epoxides with allyl and propargyl alcohols, aniline and thiophenol in the presence of catalytic amounts of B(C 6F 5) 3 has been developed. Benzyl, tetrahydropyranyl, tert-butyldimethyl silyl protecting groups were stable under the reaction conditions....

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Bibliographic Details
Published in:Tetrahedron letters 2002-05, Vol.43 (21), p.3801-3803
Main Authors: Chandrasekhar, S., Raji Reddy, Ch, Nagendra Babu, B., Chandrashekar, G.
Format: Article
Language:English
Subjects:
amino alcohols
catalysts
cleavage reactions
epoxides
hydroxy ethers
hydroxy sulfides
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Summary:A highly effective protocol for ring opening of epoxides with allyl and propargyl alcohols, aniline and thiophenol in the presence of catalytic amounts of B(C 6F 5) 3 has been developed. Benzyl, tetrahydropyranyl, tert-butyldimethyl silyl protecting groups were stable under the reaction conditions. Graphic
ISSN:0040-4039
1873-3581
DOI:10.1016/S0040-4039(02)00703-7