An efficient access to the optically active manzamine tetracyclic ring system

The highly stereoselective synthesis of the optically active tetracyclic core 2 of Manzamine A 1 was achieved via the Diels-Alder reaction of dihydropyridinone 12b, derived from L-serine, with siloxydienes, followed by sequential new and conventional pathways. [Display omitted]

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Bibliographic Details
Published in:Tetrahedron letters 1999, Vol.40 (1), p.113-116
Main Authors: Uchida, Hideharu, Nishida, Atsushi, Nakagawa, Masako
Format: Article
Language:English
Subjects:
Alkaloids
Asymmetric Synthesis
Azocines
Cycloadditions
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Description
Summary:The highly stereoselective synthesis of the optically active tetracyclic core 2 of Manzamine A 1 was achieved via the Diels-Alder reaction of dihydropyridinone 12b, derived from L-serine, with siloxydienes, followed by sequential new and conventional pathways. [Display omitted]
ISSN:0040-4039
1873-3581
DOI:10.1016/S0040-4039(98)80033-6