Chiral α,ω-diaminoethers derived from d-mannitol and l-treitol as building blocks for the synthesis of macrocyclic compounds possessing 1,3-benzenedicarboxamide or 2,6-pyridinedicarboxamide subunits

Three new chiral α,ω-diaminoethers, derivatives of d-mannitol and l-treitol, possessing C 2 symmetry are prepared. The α,ω-diaminoethers were applied to the macrocyclization reaction under non-high-dilution conditions, which afforded chiral macrocyclic diamides possessing either 2,6-pyridinedicarbox...

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Bibliographic Details
Published in:Tetrahedron: asymmetry 2001-07, Vol.12 (12), p.1763-1769
Main Authors: Piątek, Piotr, Gruza, Mariusz M., Jurczak, Janusz
Format: Article
Language:English
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Summary:Three new chiral α,ω-diaminoethers, derivatives of d-mannitol and l-treitol, possessing C 2 symmetry are prepared. The α,ω-diaminoethers were applied to the macrocyclization reaction under non-high-dilution conditions, which afforded chiral macrocyclic diamides possessing either 2,6-pyridinedicarboxamide or 1,3-benzenedicarboxamide moieties. Graphic
ISSN:0957-4166
1362-511X
DOI:10.1016/S0957-4166(01)00309-3