Enhancement of the Cr(VI) adsorption and photocatalytic reduction activity of g-C3N4 by hydrothermal treatment in HNO3 aqueous solution

• Published in: Applied catalysis. A, General General, 2016-07, Vol.521, p.9-18
• Main Authors: Wei, Hongtao, Zhang, Qian, Zhang, Yongcai, Yang, Zhanjun, Zhu, Aiping, Dionysiou, Dionysios D.
• Format: Article
• Language: English
• Subjects: Adsorption; Graphitic carbon nitride; Hexavalent chromium; Hydrothermal treatment; Photocatalytic reduction
• ISSN: 0926-860X; 1873-3875
• DOI: 10.1016/j.apcata.2015.11.005

[Display omitted] •Hydrothermal treatment in HNO3 aqueous solution is adopted to modify g-C3N4.•Treated g-C3N4 exhibits enhanced adsorption and photocatalytic reduction of Cr(VI).•Hydrothermal treatment conditions affect the structure and performance of g-C3N4.•Reasons for improved performance of treated g-C3N4 are discussed.•Different photocatalytic Cr(VI) reduction mechanisms over g-C3N4 and treated g-C3N4. An effective and environmental-friendly method was adopted to enhance the Cr(VI) adsorption and photocatalytic reduction activity of g-C3N4, which was prepared by thermal condensation of melamine. The enhancement was realized by hydrothermal treatment of g-C3N4 in 1.9–7.6mol/L HNO3 aqueous solutions at 80–120°C for 3–12h. The compositions, structures and physiochemical properties of the hydrothermally treated g-C3N4 were characterized by X-ray diffraction, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, scanning electron microscopy, transmission electron microscopy, N2 adsorption/desorption isotherms, Zeta potential analysis, UV–vis diffuse reflectance spectroscopy and photocurrent measurement, and their dark adsorption and visible-light (wavelength >420nm)-driven photocatalytic reduction of Cr(VI) in aqueous solution were tested. It was found that the hydrothermally treated g-C3N4 exhibited significantly enhanced Cr(VI) adsorption and photocatalytic reduction activity than g-C3N4. Moreover, larger concentration of HNO3 aqueous solution, higher hydrothermal temperature or longer treatment time resulted in higher Cr(VI) adsorption and photocatalytic reduction activity of the hydrothermally treated g-C3N4. The reasons accounting for the enhanced Cr(VI) adsorption and photocatalytic reduction activity of the hydrothermally treated g-C3N4 were discussed, and the different mechanisms for the photocatalytic reduction of Cr(VI) over g-C3N4 and the hydrothermally treated g-C3N4 were also proposed.