FeOx-supported gold catalysts for catalytic removal of formaldehyde at room temperature

• Published in: Applied catalysis. B, Environmental Environmental, 2014-07, Vol.154-155, p.73-81
• Main Authors: Chen, Bing-bing, Zhu, Xiao-bing, Crocker, Mark, Wang, Yu, Shi, Chuan
• Format: Article
• Language: English
• Subjects: Catalysis; Catalytic oxidation; Chemistry; Exact sciences and technology; Formaldehyde; General and physical chemistry; Gold; Iron oxide; Room temperature; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
• ISSN: 0926-3373; 1873-3883
• DOI: 10.1016/j.apcatb.2014.02.009

•This paper firstly reported complete oxidation of HCHO into CO2 and H2O over Au/FeOx-C200 catalyst at room temperature.•A certain amount of water was essential for complete oxidation of HCHO at room temperature.•Calcination temperature applied exerts a significant influence on the catalytic activity of Au/FeOx catalyst. FeOx-supported Au catalysts prepared by co-precipitation (CP) were investigated for catalytic HCHO oxidation. The applied calcination temperature was found to greatly influence both the chemical properties and microstructure of the catalysts. Characterization using XRD, H2-TPR and XPS suggested that lower calcination temperature improves the reducibility of the catalysts, and favors the presence of surface hydroxyl groups. Consequently, an Au/FeOx catalyst calcined at 200°C afforded 100% conversion of HCHO into CO2 and H2O at room temperature and under humid air. In situ DRIFTs studies suggested that the moisture was essential for deep oxidation of the formate intermediates into CO2 and H2O, this being the rate limiting step for catalytic HCHO oxidation.