Working-fluid selection and performance investigation of a two-phase single-reciprocating-piston heat-conversion engine

• Published in: Applied energy 2017-01, Vol.186, p.376-395
• Main Authors: Oyewunmi, Oyeniyi A., Kirmse, Christoph J.W., Haslam, Andrew J., Müller, Erich A., Markides, Christos N.
• Format: Article
• Language: English
• Subjects: Combined heat and power; Off-grid power generation; Prime mover; Renewable-heat conversion; Unsteady heat-engine; Waste-heat recovery
• ISSN: 0306-2619; 1872-9118
• DOI: 10.1016/j.apenergy.2016.05.008

•A dynamic model of the Up-THERM two-phase thermofluidic oscillator heat converter is presented.•The working-fluid saturation pressure and vapour-phase density are important in describing the engine’s performance.•Water and forty-five organic working-fluids are considered in a pre-specified Up-THERM design with a heat source at 360°C.•R113 and i-hexane are identified as optimal working fluids in terms of maximizing the engine’s power output.•Ammonia, R245ca and butane are attractive working fluids over a wider range of heat-source temperatures. We employ a validated first-order lumped dynamic model of the Up-THERM heat converter, a two-phase unsteady heat-engine that belongs to a class of innovative devices known as thermofluidic oscillators, which contain fewer moving parts than conventional engines and represent an attractive alternative for remote or off-grid power generation as well as waste-heat conversion applications. We investigate the performance of the Up-THERM with respect to working-fluid selection for its prospective applications. An examination of relevant working-fluid thermodynamic properties reveals that the saturation pressure and vapour-phase density of the fluid play important roles in determining the performance of the Up-THERM – the device delivers a higher power output at high saturation pressures and has higher exergy efficiencies at low vapour-phase densities. Furthermore, working fluids with low critical temperatures, high critical pressures and exhibiting high values of reduced pressures and temperatures result in designs with high power outputs. For a pre-specified Up-THERM design corresponding to a target (CHP prime-mover) application with a heat-source temperature of 360°C, water is compared with 45 other pure working fluids. When maximizing the power output, R113 is identified as the optimal fluid, followed by i-hexane. Fluids such as siloxanes and heavier hydrocarbons are found to maximize the exergy and thermal efficiencies. The ability of the Up-THERM to convert heat over a range of heat-source temperatures is also investigated, and it is found that the device can deliver in excess of 10kW when utilizing thermal energy at temperatures above 200°C. Of all the working fluids considered here, ammonia, R245ca, R32, propene and butane feature prominently as optimal and versatile fluids delivering high power over a wide range of heat-source temperatures.