Graphical statistics to explore the natural and anthropogenic processes influencing the inorganic quality of drinking water, ground water and surface water

• Published in: Applied geochemistry 2018-01, Vol.88, p.133-148
• Main Authors: Flem, Belinda, Reimann, Clemens, Fabian, Karl, Birke, Manfred, Filzmoser, Peter, Banks, David
• Format: Article
• Language: English
• Subjects: Boxplot; Compositional data; Cumulative distribution function; European bottled water; European surface water; European tap water; Groundwater; Heatmap
• ISSN: 0883-2927; 1872-9134
• DOI: 10.1016/j.apgeochem.2017.09.006

Plots of cumulative distribution functions (CDF) are a simple but powerful exploratory data analysis (EDA) tool to evaluate and compare statistical data distributions. Here, empirical CDF plots are used to compare results of four large (476–884 samples) national-to continental-scale inorganic water chemistry data sets: (1) European surface water, (2) European tap water, (3) European bottled waters as a proxy for groundwater and (4) Norwegian crystalline bedrock rock groundwater, all analysed at the same laboratory, albeit at different times. For many parameters (e.g., Ba, Cl−, K, SO42−) median values and ranges are, given the differing origins and, in some cases, treatment processes of the waters, surprisingly comparable. Unusually high concentrations of some other elements (e.g., B, Be, Br, Cs, F−, Ge, Li, Rb, Te and Zr) appear to be characteristic of deeper-seated, mature groundwaters. Other influences that can be inferred include contamination from well construction or plumbing materials (Cu, Pb, Zn – in tap waters, bottled waters and Norwegian groundwaters), water treatment (Fe, Mn – in tap- and Norwegian groundwater), bottle materials (Sb - bottled waters). The empirical CDF plots also reveal analytical issues for some elements (excessive rounding, element interferences). The best reference for natural and uncontaminated ’water’ is probably provided by the mineral water samples, representing ‘deep groundwater’ at the European scale. •Cumulative distribution function plots are a powerful exploration data analysis tool.•Despite different origins of waters, median values and ranges are for many elements comparable.•High concentration of B, Be, Br, Cs, F−, Ge, Li, Rb, Te and Zr characterise deeper-seated, mature groundwaters.•Correlation heatmaps with dendrograms unveils unexpected elemental correlations from plumbing materials.