Catalytic stability and surface analysis of microcrystalline Ni3Al thin foils in methanol decomposition

• Published in: Applied surface science 2014-02, Vol.293, p.169-176
• Main Authors: Michalska-Domańska, Marta, Norek, Małgorzata, Jóźwik, Paweł, Jankiewicz, Bartłomiej, Stępniowski, Wojciech J., Bojar, Zbigniew
• Format: Article
• Language: English
• Subjects: Carbon deposit; Catalytic stability; Condensed matter: electronic structure, electrical, magnetic, and optical properties; Condensed matter: structure, mechanical and thermal properties; Cross-disciplinary physics: materials science; rheology; Exact sciences and technology; Methanol decomposition; Ni nanoparticles; Ni3Al thin foils; Physics
• ISSN: 0169-4332; 1873-5584
• DOI: 10.1016/j.apsusc.2013.12.124

•The catalytic activity of the Ni3Al thin foils in methanol decomposition was investigated.•The catalytic stability tests at 500°C were done.•The methanol conversion was 90% after 17h reaction.•Ni nanoparticles along and at the ends of nanofibers were observed. The research on the development of solid state catalyst is presented. In this study, the catalytic activity and catalytic stability tests of the Ni3Al thin intermetallic foils in methanol decomposition were investigated. The catalytic activity of Ni3Al started above 300°C, and reached a maximum of methanol conversion (94%) at 500°C. Carbon deposit formed during the catalytic tests was analyzed in details by SEM, BET, XRD, and Raman spectroscopy. It was found that the carbon deposit consists of well crystallized, curved multi-walled carbon nanotubes, and amorphous carbon, perhaps in the form of nanofibers, without single-walled carbon nanotubes. Despite the presence of various forms of carbon on the Ni3Al surface, the catalyst provides a good catalytic stability: even after 17h of the reaction, the methanol conversion is 90%. At the ends of the obtained nanotubes/nanofibers one can see Ni nanoparticles. Moreover, it has been proven that the Ni nanoparticles are situated inside the carbon nanofibers/nanotubes, as well. The mechanism of the carbon deposit growth on Ni3Al thin foils was proposed.