A well-designed CoTiO3 coating for uncovering and manipulating interfacial compatibility between LiCoO2 and Li1.3Al0.3Ti1.7(PO4)3 in high temperature zone

• Published in: Applied surface science 2020-10, Vol.526, p.146601, Article 146601
• Main Authors: Li, Shi-Cai, Yu, Jin-Gang
• Format: Article
• Language: English
• Subjects: All solid state lithium ion battery; Coating; CoTiO3; Failure mechanism; Interface; Lithium aluminum titanium phosphate
• ISSN: 0169-4332; 1873-5584
• DOI: 10.1016/j.apsusc.2020.146601

Based on the understanding of the interaction between the cathode material (LCO) and the ceramic electrolyte (LATP), the four key steps involved in the reaction mechanism were discussed in detail. We found that the chemical reactions between LCO and LATP at high-temperature could be well suppressed by introducing CoTiO3 as an efficient inhibition coating. High-density solid-state electrodes were prepared at high temperature, which exhibited high electrochemical performance in LCO-LATP-LiIn solid-state batteries. [Display omitted] •Unexpected reaction between LiCoO2 and LATP at high temperatures.•Four step solid state reaction mechanism.•CoTiO3 thin layer as reaction suppressant between LCO and LATP in lithium ion batteries. The unexpected chemical reaction between LiCoO2 (LCO) and Li1.3Al0.3Ti1.7(PO4)3 (LATP) in high temperature sintering process was studied by a well-designed stoichiometric ratio method. The species, content, color, interface morphology, element distribution and electrode impedance were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS) and X-ray photoelectron spectroscopy (XPS). Various electrochemical analyses such as charge/discharge, cycle life test and electrochemical impedance spectroscopy (EIS) were conducted to evaluate the cell performance. Based on the understanding of the interaction between the cathode material (LCO) and the ceramic electrolyte (LATP), the four key steps involved in the reaction mechanism were discussed in detail. We found that the high-temperature chemical reactions between LCO and LATP could be well suppressed by introducing CoTiO3 as an efficient inhibition coating. High-density solid-state electrodes were prepared at high temperature, which exhibited high electrochemical performance in LCO-LATP-LiIn solid-state batteries.