Bimetal selenide NiSe/ZnSe heterostructured nanoparticals decorated porous g-C3N4 nanosheets to boost H2 evolution and urea synthesis

• Published in: Applied surface science 2022-11, Vol.602, p.154329, Article 154329
• Main Authors: Tian, Yue, Wu, You, Liang, Hongye, Zhao, Bowen, Jin, Yingxue, Liu, Jiawen, Li, Zhonghua
• Format: Article
• Language: English
• Subjects: Carbon nitride; H2 evolution; Photocatalysis; Urea synthesis; ZnxNi1−xSe
• ISSN: 0169-4332; 1873-5584
• DOI: 10.1016/j.apsusc.2022.154329

[Display omitted] •Heterostructured NiSe/ZnSe nanoparticles were prepared by one-step selenization.•NiSe/ZnSe/g-C3N4 shows superior photocatalytic performance compared to g-C3N4.•NiSe/ZnSe heterojunction plays two important roles - constructing heterojunction and cocatalyst.•The synergistic effect of heterojunction and cocatalyst is more conducive to the separation and transfer of photocarries. Promoting the separation and transfer of photocarries is very critical in designing an effective photocatalyst. In this study, a novel bimetal selenide ZnxNi1−xSe with NiSe/ZnSe heterostructure prepared by one-step selenization to construct ternary catalytic system NiSe/ZnSe/g-C3N4 (ZnxNi1−xSe/g-C3N4). Consequently, the photocatalytic activity of ZnxNi1−xSe/g-C3N4 is greatly enhanced and higher than that of binary ZnSe/g-C3N4 or NiSe/g-C3N4. The hydrogen production rate of 7 % Zn0.7Ni0.3Se/g-C3N4 reaches 410.15 μmol h−1 g−1, which is 34 times of pure g-C3N4 and 1.5 times of 1 % Pt/g-C3N4. For urea synthesis, 10 % Zn0.7Ni0.3Se/g-C3N4 show the highest urea synthesis rate of 1.12 μmol h−1 g−1, which is about 6 times of pure g-C3N4. The intrinsic mechanism analysis indicates that bimetal selenide NiSe/ZnSe heterojunction plays two roles in ZnxNi1−xSe/g-C3N4 system. Both ZnSe and g-C3N4 forms a type II heterojunction to effectively separate photocarriers. Meanwhile, NiSe provides hydrogen evolution active sites due to its smaller H adsorption free energy, making hydrogen more easily generated and released on it. The synergistic effect of ZnSe/g-C3N4 type II heterojunction and NiSe co-catalyst is more conducive to the separation and transfer of photocarries, thereby resulting in a remarkably enhanced activity. This work provides a unique construction method to design an effective ternary photocatalysts with a double stimulative effect.