Photo-induced liquid-based slippery materials for highly efficient particle aggregation

• Published in: Applied surface science 2025-02, Vol.682, p.161638, Article 161638
• Main Authors: Min Yoon, Seong, Young Kim, Woo, Joo Han, Yoo, Na Yoon, Seo, Jeong, Jun-ho, Kim, Seok, Tae Cho, Young
• Format: Article
• Language: English
• Subjects: Colloidal droplet; Droplet evaporation; Particle aggregation; Photo-induced process; Slippery interface
• ISSN: 0169-4332
• DOI: 10.1016/j.apsusc.2024.161638

[Display omitted] •The slippery organogel (SOG) surface was rapidly fabricated using a photo-induced process.•The SOG surface effectively aggregated biological droplets containing organic particles.•Particles aggregated into a confined area can improve detection sensitivity and reproducibility. The drying of droplets containing non-volatile solutes presents significant potential for sensing applications, including disease diagnosis, and the detection of harmful substances. Colloidal droplets form various patterns on surfaces after evaporation, and controlling the deposited patterns to achieve the desired characteristics is crucial in sensing applications. In this study, we propose a novel approach that employs a slippery organogel (SOG) surface that can be rapidly fabricated based on a photo-induced process to enhance the sensitivity and reproducibility during detection. The SOG forms a thin lubricating layer on the surface, which reduces the pinning of the three-phase contact line, causing the aggregation of particles within a confined area. To analyze the aggregation characteristics of colloidal droplets on the SOG, we compared the deposited particles after evaporating four types of colloidal droplets on the following different surfaces: hydrophilic, hydrophobic, organogel (OG), and SOG. The SOG surface demonstrated a superior particle aggregation capability across various colloidal droplets, which is crucial for the future development of high-sensitivity detection technologies.