Synthesis of the CaAl2O4 nanoceramic compound using high-energy ball milling with subsequent annealing

• Published in: Advanced powder technology : the international journal of the Society of Powder Technology, Japan Japan, 2014-01, Vol.25 (1), p.338-341
• Main Authors: Shiri, S., Abbasi, M.H., Monshi, A., Karimzadeh, F.
• Format: Article
• Language: English
• Subjects: Annealing; CaAl2O4; Milling; Nanoceramic
• ISSN: 0921-8831; 1568-5527
• DOI: 10.1016/j.apt.2013.05.012

[Display omitted] •Synthesis of CaAl2O4 was successfully achieved by milling and annealing.•No CaAl2O4 formed during ball milling even after 100h.•The CaAl2O4 was obtained by milling the sample for 100h and annealing at 1200°C.•CaAl2O4 was formed at a temperature 250°C lower than the temperature commonly used.•The product particle size was nanometric as shown by TEM. Monocalcium aluminate, CaAl2O4, is the main constituent of calcium alumina cements which have found wide applications in refractory industries. In the present work, CaAl2O4 nanoceramic compound was produced by high-energy ball milling of the oxide powders followed by annealing. The phase evolution and microstructural changes of the powders during the process were investigated by means of X-ray diffraction, scanning electron microscopy and transmission electron microscopy. The results showed that no CaAl2O4 was formed during ball milling even after 100h. By subsequent annealing, the nucleation and growth of CaAl2O4 took place at 1000°C after 2h. Depending on milling time, the amount of CaAl2O4 increased with increasing annealing temperature. The CaAl2O4 single phase was obtained by milling the sample for 100h and subsequently annealing at 1200°C for 2h. The quantitative phase analysis was used to measure CaAl2O4 phases in these processes. The average particle diameter of the sample milled for 100h and annealed at 1200°C was found to be less than 100nm as measured by transmission electron microscopy.