Polymerization pyrolysis derived self-supported Mo-Ni-O electrocatalyst for oxygen evolution

• Published in: Catalysis today 2019-06, Vol.330, p.246-251
• Main Authors: Cao, Shuang, Wu, Zhijiao, Fu, Bing, Yu, Haining, Piao, Lingyu
• Format: Article
• Language: English
• Subjects: Electrocatalysis; Molybdenum-nickel oxide; Oxygen evolution reaction; Polymerization pyrolysis; Self-support
• ISSN: 0920-5861; 1873-4308
• DOI: 10.1016/j.cattod.2018.03.023

[Display omitted] •Introduce an in-situ polymerization strategy to construct carbon layer.•Construct a novel self-supported Mo-Ni-O/carbon core/shell electrode.•Excellent electron transfer efficiency between active species and substrate.•Bimetallic Mo-Ni oxides demonstrate enhanced OER efficiency. Development of efficient, low cost, and durable electrocatalysts for oxygen evolution is considered as the key challenge to realize large-scale water splitting. In this work, a novel approach for the synthesis of self-supported carbon coated molybdenum oxide catalyst is reported. An in-situ polymerization strategy is introduced to construct the conductive polypyrrole (PPy) growing on carbon cloth (CC). Subsequently, Mo-O nanoparticles are formed and embedded into the carbon scaffold to form the self-supported oxygen evolution reaction (OER) catalyst on CC with no binders. Further, introducing the metal Ni led to a positive synergistic effect and the Mo-Ni-based bimetallic oxide exhibited an extremely low overpotential of ∼320 mV to reach a current density of 10 mA cm−2, which is much lower than the values of most reported transition-metal-based electrocatalysts for OER. Such excellent OER activity is attributed to the well-dispersed and abundant Mo-Ni-O nanoparticles (NPs) on CC and synergistic contribution of Mo-Ni electron density redistribution and excellent electron transfer efficiency between active species and substrate.