Loading…
Strategy to enhance the electrochemical performance of silicon oxycarbide as anodes in sodium-ion batteries
[Display omitted] •Highest capacity of SiOC in NIB was achieved using 1 M NaOTf in diglyme electrolyte.•Lower cell overpotential was observed using the diglyme electrolyte.•Ultrathin and inorganic SEI layer was the main reason for high capacity. Na+-ion storage capacity of silicon oxycarbides (SiOCs...
Saved in:
Published in: | Chemical engineering journal (Lausanne, Switzerland : 1996) Switzerland : 1996), 2022-06, Vol.438, p.135411, Article 135411 |
---|---|
Main Authors: | , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
Summary: | [Display omitted]
•Highest capacity of SiOC in NIB was achieved using 1 M NaOTf in diglyme electrolyte.•Lower cell overpotential was observed using the diglyme electrolyte.•Ultrathin and inorganic SEI layer was the main reason for high capacity.
Na+-ion storage capacity of silicon oxycarbides (SiOCs) can be enhanced by incorporating an ether-based electrolyte. Nonporous SiOC micron-sized particles in a sodium trifluoromethane sulfonate-diglyme electrolyte exhibit a more enhanced storage capacity (287 mAh g−1) in addition to a small capacity decay (0.002%) after 10,000 cycles. On applying a constant current constant voltage (CCCV) mode, the capacity increased to 322 mAh g−1, approaching its theoretically estimated value. In contrast to conventional ester-based electrolytes, using a diglyme-based ether electrolyte produced an ultrathin and inorganic-based solid electrolyte layer on the electrode surface. This reduces cell overpotential and volume expansion of the electrode. This study provides a rational strategy to design high-performance NIB cells. |
---|---|
ISSN: | 1385-8947 1873-3212 |
DOI: | 10.1016/j.cej.2022.135411 |