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Dual 3D networks of graphene derivatives based polydimethylsiloxane composites for electrical insulating electronic packaging materials with outstanding electromagnetic interference shielding and thermal dissipation performances
•3D GnP@PDMS/GF composites with integrating double-network structure were fabricated.•The porous structured 3D GnP@PDMS contributes to higher attenuation of electromagnetic waves.•Dual 3D network provides channel for electron and phonon transmission in PDMS composites.•The composites possess excelle...
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Published in: | Chemical engineering journal (Lausanne, Switzerland : 1996) Switzerland : 1996), 2023-04, Vol.462, p.142017, Article 142017 |
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Main Authors: | , , , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | •3D GnP@PDMS/GF composites with integrating double-network structure were fabricated.•The porous structured 3D GnP@PDMS contributes to higher attenuation of electromagnetic waves.•Dual 3D network provides channel for electron and phonon transmission in PDMS composites.•The composites possess excellent EMI SE, thermal conductivity and electrical insulation.•The multifunctional 3D GnP@PDMS/GF composites have great potential for electronic packaging devices.
Research on electronic packaging materials with high electromagnetic interference (EMI) shielding, thermal conductivity, and electrical insulating properties has been flourishing in recent years. In this work, dual three-dimensional (3D) structures of graphene nanoplatelets (GnP) and graphene fluoride (GF) were fabricated in the polydimethylsiloxane (PDMS) composites for electronic packaging materials with superior EMI shielding effectiveness (SE), thermal conductivity, and electrically insulating. The first 3D structure of the porous GnP@PDMS foams was fabricated using the sugar template method. The GF/PDMS solution was then infiltrated into the GnP@PDMS foam by the vacuum infiltration method to create the second 3D network of GF in the GnP@PDMS/GF composites. The prepared porous GnP30@PDMS foam exhibits an EMI SE of 51.26 dB with 30 wt% of GnP. In addition, the introduction of the second 3D network of GF/PDMS plays a vital role to improve the thermal conductivity and electrical insulating properties of the GnP30@PDMS/GF composites. The GnP30@PDMS/GF8 composites showed a thermal conductivity of 1.47 W·m−1·K−1 which is enhanced by 568 % in comparison to the pure PDMS and excellent electrical insulating properties as high as 2.82 × 10−10 S·cm−1 and maintained high EMI SE of 50.13 dB. The extraordinary EMI SE of the GnP@PDMS/GF composites is favorably correlated to the porous interconnected network of GnP while the enhanced thermal conductivity is attributed to the dual 3D thermoconductive channels of GnP and GF. Additionally, the GnP@PDMS/GF8 composites are demonstrated to have outstanding mechanical flexibility, thermal stability, and heat dissipating capability. Therefore, the developed GnP@PDMS/GF composites have great prospects in the field of electronic packaging materials. |
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ISSN: | 1385-8947 1873-3212 |
DOI: | 10.1016/j.cej.2023.142017 |