Study on the minimum miscibility pressure and phase behavior of CO2–shale oil in nanopores

• Published in: Chemical engineering journal (Lausanne, Switzerland : 1996) Switzerland : 1996), 2024-10, Vol.497, p.154493, Article 154493
• Main Authors: Wang, Yuhan, Lei, Zhengdong, Sun, Linghui, Pan, Xiuxiu, Liu, Yishan, Xu, Zhenhua, Zheng, Xiaoyu, Wang, Yanwei, Liu, Pengcheng
• Format: Article
• Language: English
• Subjects: Confinement Effect; Minimum Miscibility Pressure; Nanofluidic; Nanopores; Phase Behavior
• ISSN: 1385-8947
• DOI: 10.1016/j.cej.2024.154493

•An innovative nanofluidic chip was designed and developed for measuring the minimum miscibility pressure of CO2-shale oil.•A novel thermodynamic model of phase equilibrium was developed by integrating simplified local density functional theory.•The phase behavior of CO2-shale oil and the variation rule of MMP at different scale pore sizes were explored. In recent years, CO2 enhanced oil recovery has gained traction in shale oil reservoirs. Shale oil reservoirs are characterized by numerous nanopores, where shale oil exhibits unique phase behavior due to nano–confinement effects. Traditional theoretical model and microfluidic experiment often fail to accurately depict the minimum miscible pressure (MMP) of CO2–shale oil in nanopores. In this study, nanofluidic experiments were conducted to investigate the MMP of CO2–alkanes in single pore channels and porous media channels with depths of 30 nm and 100 nm. Additionally, a novel thermodynamic model of gas–liquid–adsorbed phase equilibrium, which considers the capillary force and the shift in the critical property, was developed by integrating simplified local density functional theory. The feasibility of the method was determined by comparing the measured MMP with the MMP obtained using the newly established thermodynamic model, resulting in errors of 10.804 % and 5.545 %. Finally, phase behavior and MMP for two typical oil samples in block A in China were conducted using the newly established thermodynamic model. The results revealed that as the pore radius decreases, the area of the two–phase region enclosed by the phase envelope contracts progressively. In addition, the saturation pressure decreases gradually for shale oil with a higher content of light components as the molar fraction of the injected CO2 increases, whereas for shale oil with higher heavy component content, it increases as the CO2 molar fraction increases. The MMP of CO2–shale oil in 10 nm pores is 70.188 bar at 392.75 K of sample 1 and 83.007 bar at 374.72 K of sample 2. Compared to the bulk phase, the MMP was reduced by 63.76 % and 57.64 %.