Synthesis and characterisation of Y2O3 using ammonia oxalate as a precipitant in distillate pack co-precipitation process

• Published in: Ceramics international 2018-10, Vol.44 (15), p.18693-18702
• Main Authors: Foo, Yuan Teng, Abdullah, Ahmad Zuhairi, Horri, Bahman Amini, Salamatinia, Babak
• Format: Article
• Language: English
• Subjects: Ammonium oxalate; Nanoparticles; Precipitation; Yttria; Yttrium oxide
• ISSN: 0272-8842; 1873-3956
• DOI: 10.1016/j.ceramint.2018.07.098

Pure cubic phase yttrium oxide or yttria (Y2O3) nanoparticles were successfully synthesised via the co-precipitation method in a distillate pack, followed by calcination of the precursor, yttrium oxalate (Y2(C2O4)3) in a furnace. The co-precipitation reaction temperature was varied between room temperature and 100 °C for various reaction durations ranging between 0.5 and 3 h. The as-synthesised precursor was characterised using a thermogravimetric analyser (TGA) and Fourier transform infrared spectrometer (FTIR). The Y2O3 nanoparticles obtained from the calcination of the precursor at various calcination conditions (temperature ranged from 500 to 800 °C for 2–8 h) were characterised using a field emission scanning electron microscope (FESEM), a transmission electron microscope (TEM), X-ray diffraction (XRD), FTIR, a Raman spectrometer, and Brunauer–Emmett–Teller analyser (BET). It was concluded from these characterisations that the optimum processing parameters for pure Y2O3 nanoparticles are co-precipitation reaction at 40 °C for 1 h, followed by calcination at 650 °C for 4 h. This method yielded semispherical Y2O3 nanoparticles with crystallite size ranging between 7 and 21 nm and a large specific surface area of 7.40 m2/g.