Preparation of Mn–Zn ferrite ceramic using stereolithography 3D printing technology

• Published in: Ceramics international 2022-03, Vol.48 (5), p.6923-6932
• Main Authors: Hu, Yifan, Zou, Bin, Xing, Hongyu, Liu, Jikai, Chen, Qinghua, Wang, Xinfeng, Li, Lei
• Format: Article
• Language: English
• Subjects: Curing properties; Hysteresis loop; Mn-Zn ferrite; Printing parameters; Stereolithography
• ISSN: 0272-8842; 1873-3956
• DOI: 10.1016/j.ceramint.2021.11.248

In this work, tailored Mn–Zn ferrite ceramics are prepared by stereolithography (SLA) 3D printing technology, and its performances are measured utilizing the printing accuracy, magnetic properties, density, and microstructures. The major obstacle forming difficultly by single curing of self-made ferrite pastes with increasing solid content in the printing process is removed by using six scanning numbers. In addition, the prediction formulas of the linewidth and curing depth are established. The printing process parameters, namely scanning space, scanning speed, and laser power, are optimized at 2 μm, 2500 mm/s, and 240 mW, respectively. The size of convex platform bigger than 1 mm × 1.2 mm possessing circular and square holes with a diameter and a side length of 0.2 mm can be printed using the printing process parameters above. Specifically, the sintering temperature and holding time below 1200 °C and 90 min, respectively, are optimized conducive limits. The sintered parts show a density of 4.04 g/cm3 and a saturation magnetization of 58.6 emu/g, along with a small value of coercivity and remanence. The SLA-3D printing, debinding, and sintering technologies can print the complex shapes Mn–Zn ferrite ceramics using the proposed process.