Increasing thermodynamic stability and electrochemical performance of IT-SOFC cathodes based on Ln2MO4 (Ln = La, Pr; M = Ni, Cu)

• Published in: Ceramics international 2024-10, Vol.50 (20), p.40453-40463
• Main Authors: Gilev, A.R., Sukhanov, K.S., Kiselev, E.A., Sobol, M.E., Cherepanov, V.A.
• Format: Article
• Language: English
• Subjects: B. Electron microscopy; B. X-ray methods; C. Impedance; E. Electrodes
• ISSN: 0272-8842
• DOI: 10.1016/j.ceramint.2024.04.176

La2-xPrxNi1-yCuyO4+δ (x = 0.5, 1, 1.5, y = 0.4, 0.6, 0.8) were synthesized by a citrate-nitrate method and studied as cathode materials for IT-SOFCs by Electrochemical Impedance Spectroscopy (EIS) in symmetrical cells based on the Ce0.8Sm0.2O2-δ (SDC) and La28-zW4+zO54+1.5z (z = 0.85, LWO) electrolytes. Phase identification and crystal structure analysis by means of X-ray powder diffraction (XRPD) shows that solubility of copper y decreases with the increase in praseodymium content x due to increasing structural distortions. Thermodynamic stability of La2-xPrxNi1-yCuyO4+δ at intermediate temperatures in air tends to decrease with praseodymium doping level x and increases with copper substitution for nickel y. Oxides with x = 0.5 and 0.6≤y ≤ 0.8 are shown to be thermodynamically stable at 700 °C in air. Electrochemical performance of the La2-xPrxNi1-yCuyO4+δ electrodes improves with praseodymium and copper doping. The results of EIS measurements at different temperatures and oxygen partial pressures (P(O2)) reveal that the rate-determining step of the overall electrochemical process is charge transfer, which can be a combination of surface diffusion and bulk diffusion. EIS studies in dry and wet air indicate the presence of proton conduction in the studied electrodes. The area-specific resistances (ASRs) for La2-xPrxNi1-yCuyO4+δ with x = 0.5, y = 0.6 and y = 0.8 in contact with SDC are comparable with those reported for Pr2NiO4+δ and equal to 0.07 and 0.065 Ω cm2 at 800 °C. [Display omitted] •Thermodynamic stability of La2-xPrxNi1-yCuyO4+δ (LPNC) in air increases with Cu doping.•Increase in Pr and Cu content improves the electrochemical performance of LPNC.•The overall electrochemical reaction is limited by the charge transfer in electrode.•Rate-determining step can be a combination of surface diffusion and bulk diffusion.•Impedance spectroscopy studies indicate the possibility of proton conduction in LPNC.