Realizing golden ultraviolet C emission of 265 nm by oxygen vacancies engineering for 100 % sterilization efficiency

• Published in: Ceramics international 2024-09, Vol.50 (17), p.30579-30586
• Main Authors: Wang, Cheng, Tang, Yangmin, Pu, Guiqiang, Chen, Wei, Deng, Mingxue, Wang, Jiacheng
• Format: Article
• Language: English
• Subjects: Energy transfer; Golden sterilization wavelength; Oxygen vacancies engineering; Sterilization; UVC phosphors
• ISSN: 0272-8842; 1873-3956
• DOI: 10.1016/j.ceramint.2024.05.356

Ultraviolet C (UVC) light has a great promising application in the field of sterilization. However, how to obtain efficient UVC emission with peak maximum at 265 nm that is called ‘golden sterilization wavelength’ remains a great challenge. Herein, we propose a defect-engineering strategy to obtain enhanced UVC emission at the golden sterilization wavelength of 265 nm through introducing oxygen vacancies into Pr3+ doped Ba2MgSi2O7 melilite phosphors. Combined with X-ray photoelectron spectroscopy (XPS), electron paramagnetic resonance (EPR) and thermoluminescence (TL) characterizations, it is confirmed that the calcination of Ba2MgSi2O7:Pr3+ in an inert atmosphere could efficiently increase oxygen vacancy concentration, promoting the efficient energy transfer from the melilite host to Pr3+ ions. It could lead to a significant enhancement of the luminescence intensity to 2.43 times of the initial one with less oxygen vacancies. The optimized Ba2MgSi2O7:0.4%Pr3+ phosphor could effectively inactivate 100 % of Staphylococcus aureus within 8 min, showing higher efficiency than commercially available mercury lamp. This work provides an effective solution for the design and preparation of UVC phosphors using defect engineering to achieve golden UVC emission. [Display omitted]